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1 article(s) from Pittkowski, Rebecca

Enhanced quantum yields by sterically demanding aryl-substituted β-diketonate ancillary ligands

Rebecca Pittkowski and
Thomas Strassner

Beilstein J. Org. Chem. 2018, 14, 664–671, doi:10.3762/bjoc.14.54

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Graphical Abstract

Scheme 1: Synthesis of complexes 2 and 3.

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Figure 1: ORTEP representation of 3. Thermal ellipsoids are drawn at the 50% probability level. Selected bond...

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Figure 2: UV–vis absorption spectra of complexes 2 and 3 measured in dichloromethane at room temperature.

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Figure 3: Emission spectra of complexes 2 and 3 measured at room temperature and 77 K, 2 wt % in a PMMA matri...

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Figure 4: Cyclic voltammograms of complexes 2 and 3, analyte concentration 10⁻⁴ M. Measured in DMF (0.1 M TBA...

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Figure 5: Thin films of Pt(MPIM)(acac) left, Pt(MPIM)(mes) (2) middle, and Pt(MPIM)(dur) (3) right, 2 wt % in...

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Figure 6: Photoluminescence spectra of 2 and 3 compared to the emission profile of Pt(MPIM)(acac), 2 wt % in ...

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Figure 7: Localization of spin density on the complexes Pt(MPIM)(acac) left, Pt(MPIM)(mes) (2) middle, and Pt...

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Published 21 Mar 2018

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